Synthesis, spectral and structural studies of water soluble arene ruthenium (II) complexes containing 2,2′-dipyridyl-N-alkylimine ligand

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dc.contributor.author Singh, K.S.
dc.contributor.author Kaminsky, W.
dc.date.accessioned 2011-01-04T07:01:11Z
dc.date.available 2011-01-04T07:01:11Z
dc.date.issued 2011
dc.identifier.citation Inorganica Chimica Acta, vol.365(1); 2011; 487-491
dc.identifier.uri http://drs.nio.org/drs/handle/2264/3768
dc.description.abstract A series of water soluble complexes of general formula [(Eta sup(6)-arene) Ru ((C sub(5) H sub(4) N) sub(2) CNRi) Cl) PF sub(6) have been prepared by the reaction of [[(Eta sup(6)- arene) RuCl sub(2)) sub(2)) with appropriate 2,2’-dipyridyl-N-alkylimine ligands (dpNRi) in the presence of NH sub(4) PF sub(6) (where; R = Me or Et; arene = p-cymene, C sub(6) Me sub(6), C sub(6) H sub(6)). The 2,2’-dipyridyl-N-alkylimine ligands are prepared by reaction of 2,2’-dipyridyl ketone with the corresponding alkylamine. The complexes are readily obtained as air stable yellow to dark brown solids by simple stirring at room temperature. The complexes are isolated as their hexafluorophosphate salts and characterized on the basis of spectroscopic data. The molecular structure of representative complex ((Eta sup(6)-Csub(6) Me sub(6)) Ru ((C sub(5) H sub(4) N) sub(2) C= N-Me) Cl) PF sub(6) has been determined by single crystal X-ray diffraction studies.
dc.language.iso en
dc.publisher Elsevier
dc.rights An edited version of this paper was published by Elsevier. Copyright [2011] Elsevier
dc.subject water soluble complexes
dc.subject Ruthenium
dc.subject Dimethylpyridyl ketone
dc.subject Crystal structure
dc.title Synthesis, spectral and structural studies of water soluble arene ruthenium (II) complexes containing 2,2′-dipyridyl-N-alkylimine ligand
dc.type Journal Article


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