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dc.contributor.authorSingh, K.S.
dc.contributor.authorKollipara, M.R.
dc.date.accessioned2011-07-29T07:26:11Z
dc.date.available2011-07-29T07:26:11Z
dc.date.issued2011
dc.identifier.citationJournal of Indian Chemical Society, vol.88(4); 2011; 497-504
dc.identifier.urihttp://drs.nio.org/drs/handle/2264/3883
dc.description.abstractMono and di-nuclear eta sup (6)-p-cymene ruthenium(II) complexes containing carboxylato ligand of formulation [(eta sup (6)-p-cymene)Ru(pa)Cl] and [{(eta sup (6)-p-cymene)RuCl}2 (mu-LL)] [where, pa = O sub (2)CC sub (6)H sub (4)-p-OMe (1), LL = C sub (2)O sub (4)(7) or C sub (2)CH sub (2)O sub (4)(10)] have been prepared by the reaction of [(p-cymene)RuCl sub (2)]sub (2) with the corresponding sodium salts of the carboxylic acids. Treatment of (eta sup (6)-p-cymene) ruthenium(II) carboxylato complexes with NaN sub (3) yielded azido complex [{(eta sup (6)-p-cymene)Ru(mu-N sub (3))Cl} sub (2)] whereas halide scavengers such as silver acetate, silvertrifluroacetate leads to the substitution of chlorine to give neutral complexes of formulation [{(eta sup (6)-p-cymene)RuY} sub (2)(mu-LL)](where, LL = bidentate carboxylate, Y = MeCO sub (2) or CF sub (3)CO sub (2)). Mono and di-cationic complexes were also been prepared by the treatment of complex 1 with the corresponding neutral ligands in the presence of AgBF sub (4). The complexes were fully characterized on the basis of microanalysis, FT-IR and NMR spectroscopic data
dc.language.isoen
dc.publisherThe Indian Chemical Society
dc.rightsCopyright [2011]. All efforts have been made to respect the copyright to the best of our knowledge. Inadvertent omissions, if brought to our notice, stand for correction and withdrawal of document from this repository.
dc.subjectp-cymene
dc.subjectruthenium
dc.subjectazide
dc.subjectbipyridine
dc.titleReactivity studies of eta sup (6)-p-cymene ruthenium(II) carboxylato complexes towards azide some neutral ligands
dc.typeJournal Article


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