dc.contributor.author | Singh, K.S. | |
dc.contributor.author | Kaminsky, W. | |
dc.date.accessioned | 2014-02-05T10:03:41Z | |
dc.date.available | 2014-02-05T10:03:41Z | |
dc.date.issued | 2014 | |
dc.identifier.citation | Polyhedron, vol.68; 2014; 279–286 | |
dc.identifier.uri | http://drs.nio.org/drs/handle/2264/4462 | |
dc.description.abstract | The arene ruthenium(II) azido compounds [{(p-cymene)Ru(N^O)N<sub>3</sub>}] have been prepared by the reaction of [{(p-cymene)Ru(mewN<sub>3</sub>)Cl}<sub>2</sub>] with the corresponding ligands. The ruthenium azido compounds [{(p-cymene)Ru(N^O)N<sub>3</sub>}] undergo 1,3-dipolar additions with substituted alkynes at room temperature to give the (eta<sup>6</sup>-arene) ruthenium triazolato compounds [(p-cymene)Ru(N^O){N<sub>3</sub>C<sub>2</sub>(CO<sub>2</sub>R)<sub>2</sub>}]. The compounds were characterized on the basis of FTIR, NMR (<sup>1</sup>H and <sup>13</sup>C) and the molecular structure of a representative compound has been established with the help of single crystal X-ray diffraction. | |
dc.language.iso | en | |
dc.publisher | Elsevier | |
dc.rights | An edited version of this paper was published by Elsevier. Copyright [2013] Elsevier | |
dc.subject | ligands | |
dc.subject | alkynes | |
dc.title | Arene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds | |
dc.type | Journal Article | |