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dc.contributor.authorSingh, K.S.
dc.contributor.authorKaminsky, W.
dc.date.accessioned2014-02-05T10:03:41Z
dc.date.available2014-02-05T10:03:41Z
dc.date.issued2014
dc.identifier.citationPolyhedron, vol.68; 2014; 279–286
dc.identifier.urihttp://drs.nio.org/drs/handle/2264/4462
dc.description.abstractThe arene ruthenium(II) azido compounds [{(p-cymene)Ru(N^O)N<sub>3</sub>}] have been prepared by the reaction of [{(p-cymene)Ru(mewN<sub>3</sub>)Cl}<sub>2</sub>] with the corresponding ligands. The ruthenium azido compounds [{(p-cymene)Ru(N^O)N<sub>3</sub>}] undergo 1,3-dipolar additions with substituted alkynes at room temperature to give the (eta<sup>6</sup>-arene) ruthenium triazolato compounds [(p-cymene)Ru(N^O){N<sub>3</sub>C<sub>2</sub>(CO<sub>2</sub>R)<sub>2</sub>}]. The compounds were characterized on the basis of FTIR, NMR (<sup>1</sup>H and <sup>13</sup>C) and the molecular structure of a representative compound has been established with the help of single crystal X-ray diffraction.
dc.language.isoen
dc.publisherElsevier
dc.rightsAn edited version of this paper was published by Elsevier. Copyright [2013] Elsevier
dc.subjectligands
dc.subjectalkynes
dc.titleArene ruthenium(II) azido complexes incorporating N intersection O chelate ligands: Synthesis, spectral studies and 1,3-dipolar-cycloaddition to a coordinated azide in ruthenium(II) compounds
dc.typeJournal Article


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